题目：Visible-Light-Driven Fine Chemical Synthesis Using Inexpensive Natural Gases and Hydrocarbons as Feedstocks in Batch and Flow Reactors
报告人：吴杰博士，新加坡国立大学化学系助理教授，博士生导师
时间：2018年12月27日，14点30分
地点：bet体育365官网正规报告厅
联系人：张明智 17768140501
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吴杰博士，新加坡国立大学化学系tenure-tracked助理教授，博士生导师。
教育工作经历：
2006年6月，本科毕业于北京师范大学化学系
2012年5月，博士毕业于美国波士顿大学，师从James S. Panek教授从事天然产物全合成研究，期间加入波士顿大学化学方法和分子库研究中心，在John A. Porco教授的指导下完成多样导向合成的课题
2012年7月2015年1月，美国麻省理工学院(MIT)化学系和化工系联合培养的博士后，师从Timothy F. Jamison教授和T. Alan Hatton教授从事连续流动合成的研究；
2015年5月至今，新加坡国立大学化学系，tenure-tracked的助理教授，博士生导师。
研究领域：
课题组集中于发展新的可见光诱导的催化方法学，以天然气体或者便宜易得的CH和SiH键化合物作为原料，合成具有高附加值的化学品；并同时利用微型流体管路反应器和开发新的反应器模式增强光照反应的效率，实现传统化学条件下难以达到的反应环境。在迄今三年时间内，并先后在J. Am. Chem. Soc.、Angew Chem. Int. Ed.、Chem、ACS Catal.、Chem. Sci.等杂志上发表论文19篇，申请专利2项，其中多篇文章被Angew Chem. Int. Ed.，Synfacts，X-MOL，WeeChem等所评述。
个人荣誉：
03/2017, the 4th Green & Sustainable Manufacturing Award from GSK-EDB
11/2017, Asian Core Program Lectureship Award from China in the 12th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-12).
09/2018, the Department Young Chemist Award 2018 from Department of Chemistry, National University of Singapore.
11/2018, Asian Core Program Lectureship Award from Taiwan and Thailand in the 13th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-13)
11/2018, Thieme Chemistry Journal Award (2019)
发表文章的代表作：
1.Xue, F.†; Deng, H.†; Xue, C.; Mohamed, D. K. B.; Tang, K. Y.; Wu, J.* “Reaction Discovery Using Acetylene Gas as the Chemical Feedstock Accelerated by the ‘Stop-Flow’ Micro-Tubing Reactor System” Chem. Sci. 2017, 8, 3623-3627. (†Co-first authors)
2. Zhou, R.; Liu, H.; Tao, H.; Yu, X.; Wu, J.* "Metal-free direct alkylation of unfunctionalized allylic/benzylic sp3 C–H bonds via photoredox induced radical cation deprotonation." Chem. Sci. 2017, 8, 4654-4659.This article was featured in Synfacts.
3. Deng, H.; Fan, X.; Chen, Z.; Xu, Q.; & Wu, J.* "Photo-induced nickel-catalyzed chemo- and regioselective hydroalkylation of internal alkynes with ether and amide a-hetero C(sp3)H bonds" J. Am. Chem. Soc. 2017, 139, 13579-13584.This work was highlighted by NUS FoS,Phys.org and X-MOL.
4. Zhou, R.; Goh, Y. Y.; Liu, H.; Tao, H.; Li, L.; Wu, J.* “Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si-H Activation” Angew. Chem. Int. Ed. 2017, 56, 16621-16625.This article was featured in Synfacts and X-MOL.
5. Hou, J., Ee, A., Feng, W., Xu, J.-H., Zhao, Y.,* Wu, J.* "Visible-Light-Driven Alkyne Hydro-/Carbocarboxylation Using CO2 via Iridium/Cobalt Dual Catalysis for Divergent Heterocycle Synthesis" J. Am. Chem. Soc.2018, 140, 5257-5263. This work was highlighted by X-MOL.
6. Fan, X.-Z., Rong, J.-W., Wu, H.-L., Zhou, Q., Deng, H.-P., Tan, J. D., Xue, C.-W., Wu, L.-Z., Tao, H.-R., Wu, J.* "Eosin Y as a Direct Hydrogen Atom Transfer Photocatalyst for the Functionalization of C-H Bonds" Angew. Chem. Int. Ed. 2018, 57, 8514-8518. This paper has been selected as Hot Topic in Organocatalysis and Photocatalysis.This work was highlighted by Angew. Chem. Int. Ed. (Prof. Chen Jiarong and Prof. Xiao Wenjing) and X-MOL.
7. Liu, H., Ma, L., Zhou, R., Chen, X.,* Fang, W., Wu, J.* "One-Pot Photo-Mediated Giese Reaction/Friedel-Crafts Hydroxyalkylation/Oxidative Aromatization to Access Naphthalene Derivatives from Toluenes and Enones" ACS Catal. 2018, 8, 6224-6229. This paper was highlighted by X-MOL.
8. Deng, H.-P., Zhou, Q., Wu, J.* "Micro-Tubing Reactor-Assisted Aliphatic C-H Functionalization Utilizing HCl as the Hydrogen Atom Transfer Catalyst Precursor in Conjunction with an OrganoPhotoredox Catalyst" Angew. Chem. Int. Ed.2018, 57,12661-12665. This paper was highlighted by X-MOL.
9. Li, J., Luo Y., Cheo, H. W., Lan, Y.,* Wu, J.* "Photoredox Catalysis Modulated Nickel-Catalyzed Divergent Difunctionalization of Ethylene" Chem2018, DOI: 10.1016/j.chempr.2018.10.006.
10. Hou, J., Ee, A., Cao, H., Ong, H.-W., Xu, J.-H. Wu, J.* "Visible‐Light‐Mediated Metal‐Free Difunctionalization of Alkenes with CO2 and Silanes or C(sp3)H Alkanes" Angew. Chem. Int. Ed. 2018, 57, 17220-17224.This paper has been selected as Hot Paper by Angew. Chem. Int. Ed (Topics: C-H Activation, Carbon Dioxide, and Photocatalysis).This paper was highlighted by X-MOL and WeeChem.
11. Cao, H., Jiang, H., Feng, H., Kwan, J. M. C., Liu, X., Wu, J.* "Photo-Induced Decarboxylative Heck-Type Coupling of Unactivated Aliphatic Acids and Terminal Alkenes in the Absence of Sacrificial Hydrogen Acceptors" J. Am. Chem. Soc.2018, 140, 16360-16367.
12. Ng, C. K., Toh, R. W., Lin, T. T., Luo, H.-K., Hor, T. S. A.,* Wu, J.* "Metal-salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides at ambient conditions" Chem. Sci.2019, DOI: 10.1039/C8RE00216A.